PHOTOFRAGMENT SPECTROSCOPY OF $CS_{2}$ AT 206-200 nm
Loading...
Date
1991
Authors
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
The photofragmentation of $CS_{2}$ in the region 206-200 nm has been studied under supersonic molecular beam conditions, with the S atom products being detected by vacuum ultraviolet laser-induced fluorescence. The excitation spectrum for the $S(^{1}D_{2})$ and $S(^{3}P_{2})$ products can be measured by scanning the photolysis laser over the $\bar{B} ^{1} \Sigma _{\mu}^{+}(^{1}B_{2})\leftarrow X^{1}\Sigma_{g}^{+}$ absorption system. These spectra provide information on the spectroscopy and dynamics of the predissociating B state.
Description
Author Institution: Centre for Molecular Beams and Laser Chemistry, University of Waterloo