INFRARED SPECTRA OF HCN ISOTOPES IN ARGON MATRICES
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Date
1971
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Publisher
Ohio State University
Abstract
The infrared spectra of the $^{1,2}$H$^{12,13} C$ $^{14,15} N$ isotopic species of HCN were measured in argon matrices. The discrepancy in the ratio of the C-H and C-N bond lengths compared to the gas phase, and the size of the solvent shifts of the vibrational frequencies are discussed in terms of various models for the argon- HCN interaction. The relative intensities of the isotopic frequncies in the matrix are compared to those in the gas phase.
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Author Institution: Department of Chemistry, Iowa State University