VIBRATIONAL CIRCULAR DICHROISM AND THE FIXED PARTIAL CHARGE MODEL FOR SPIRO NONADIENE

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1978

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Ohio State University

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Abstract

VCD of (+) 1,6-Spiro [4,4] nonadiene has been measured in the CH stretching region. This molecule should be ideal for analysis with the Warshel-Lifson consistent force field modified Co calculate VCD in the Schellman fixed partial charge model. Problems of this approach and sensitivity of the calculation to various parameters will be discussed.

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Author Institution: Department of Chemistry, University of Illinois at Chicago Circle; Department of Chemistry, University of Southern California

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