THE INFRARED SPECTRUM OF PRUSSIAN BLUE AND OTHER METAL-IRON CYANIDE COMPOUNDS.
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Date
1969
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Ohio State University
Abstract
The infrared spectra of Prussian blue and compounds of the type $M_{2}[Fe(CN)_{6}$ where $M = Cu, Zn$, Cd have been obtained in the region $33-4000 cm^{-1}$. In addition, Prussian blue has been spectroscopically studied in the temperature range $300^{\circ}K-4^{\circ}K$. Spectra obtained at $300^{\circ} K$ and $77^{\circ}K$ are different in the region of the Fe-C stretching motion. The infrared spectra will be correlated with the x-ray, magnetic susceptibility, and Mossbauer studies in an effort to clarify the structures of the metal-iron cyanide compounds.
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Author Institution: Department of Chemistry, Texas Technological College