SULFUR DIOXIDE AS AN INTERNAL CALIBRATION STANDARD FOR MICROWAVE SPECTROSCOPY ZEEMAN EFFECT MEASUREMENTS

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1977

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Ohio State University

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Abstract

It is proposed that the Zeeman effect of the 202→111 transition in sulfur dioxide be used as a magnetic field calibration standard. The recent accurate beam maser measurements on this transition by Ellenbroek and Dymanus1 have been confirmed by electric resonance measurements in the 111 level. The Zeeman splittings most useful for calibration purposes depend linearly on the magnetic field. For perpendicular selection rules the Zeeman coefficient is 0.5282(3) MHz/kg, and 0.3722(3) MHz/kg applies to parallel selection rules.

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1A. W. Ellenbroek and A. Dymanus, Chem. Phys. Lett. 42, 303 (1976).


Author Institution: Department of Chemistry, University of Rochester

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