INTERNAL ROTATION IN SIMPLE, UNSATURATED THIOLS AND ALCOHOLS
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Date
1985
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Publisher
Ohio State University
Abstract
The results of a study of internal rotation in the compounds XCH = CHSH and $XCH = CHOH, X = CN, H, CH_{3}$ and F, using a combination of the methods of microwave spectroscopy and ab-initio molecular orbital calculations will be described. Quite extensive relaxation of the framework of these molecules during the internal rotation of the OH or SH fragments has been identified and the significant influence of the substituent, X, on the internal rotation potential functions established.
Description
Author Institution: Department of Chemistry, University College of North Wales; Department of Chemistry, University College of North Wales