VIBRATIONAL SPECTRA AND RING-PUCKERING OF 1,3-DISILACYCLOBUTANE

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Date

1974

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Ohio State University

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Abstract

1,3-Disilacyclobutane has been prepared and preliminary vibrational spectra have been recorded. Sum and difference bands resulting from the ring-puckering mode have been observed in both infrared and Raman spectra in the $SiH_{2}$ stretching region. A preliminary potential energy function for the ring-puckering indicates a potential barrier of approximately 100 $cm^{-1}$.

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This work was supported by the Robert A. Welch Foundation.
Author Institution: Department of Chemistry, Texas A\&M University

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