ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF THE $MgC_{5}H_{5} \tilde{A} \leftarrow \bar{X}$ BANDS

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1993

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Ohio State University

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We have recorded the rotationally resolved, jet-cooled electronic spectrum of MgC5H5 (MgCp). The MgCp was produced in a free-jet expansion by simultaneous photo-ablation of a Mg target and photo-dissociation of C5H6 in a fixture attached to a pulsed valve assembly. The laser-induced fluorescence spectra of both the origin and 1601 band were recorded. The Doppler limited spectra had a linewidth of approximately 100 MHz and a rotational temperature of a few degrees Kelvin. The analysis of these spectra will be discussed.

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Author Institution: Laser Spectroscopy Facility, Department of Chemistry, The Ohio State University

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http://hdl.handle.net/1811/18552

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1990-1999