ELECTRONIC STRUCTURE OF SCANDIUM

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1972

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Ohio State University

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The band structure of scandium is studied on the basis of the SRAPW method and an interpolation scheme which uses the s, p, d type functions in the tight-binding representation. The warped muffin-tin potential was obtained from overlapping charge densities which were derived from the atomic configuration $3d4s^{2}$ with the exchange interaction based on the Slater approximation. The Hamiltonian of the interpolation scheme was parameterized in terms of 16 parameters in a two-center approximation. The results obtained for the total density of states, the factorized d density of states, etc., are in excellent agreement with the experimental results. This research was supported by the AEC, AFOSR and by ARPA through the N.U. Materials Research Center.

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Author Institution: Argonne National Laboratory; Argonne National Laboratory, Northwestern University; Argonne National Laboratory, Northwestern University

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