THE VIBRATIONAL LINES OF SOME TRIHALIDES IN THE FAR INFRARED

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1954

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Ohio State University

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Vibrational fundamentals of PCl3, PBr3 and other trihalides of the XY3 type have been measured in the spectral region of wavelengths 30μ. The band locations are presumably more precise than those obtained earlier using Raman data. Data have been obtained for SbBr3 which has heretofore not been measured. The accuracy of locating the band contour centers varies from 0.5cm−1 to rather better. Experimental details and such theoretical interpretation as can be attempted on the basis of the present extent of the data are given.

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Note. Data were obtained on the far infrared spectrograph, construction of which was supported by Wright Air Development Center.


Author Institution: Department of Physics, The Ohio State University

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http://hdl.handle.net/1811/7259

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1946-1959