INFRARED SPECTRA OF K$^+$(TRYPTAMINE)(H$_2$O)$_{n=1-4}$ AND K$^+$(TRYPTAMINE)(H$_2$O)$_{n=0-2}$Ar

Loading...
Thumbnail Image

Date

2008

Journal Title

Journal ISSN

Volume Title

Publisher

Ohio State University

Research Projects

Organizational Units

Journal Issue

Abstract

A balance of competing electrostatic and hydrogen bonding interactions directs the structure of hydrated gas-phase cluster ions. In K$^+$(Tryptamine) cluster ions, a favorable electrostatic interaction between the potassium cation and the tryptamine NH$_2$ lone pair stabilizes the high-energy Gph(in) and Gpy(in) conformers of neutral tryptamine. Previous studies of Tryptamine(H$_2$O)$_n$ clusters indicate that the hydrating water molecules stabilize the neutral minimum energy Gpy(out) tryptamine conformer. In this scheme, the first water molecule interacts directly with the NH$_2$ lone pair and is located to the side of the tryptamine monomer. By incorporating a potassium cation, however, the minimum energy tryptamine$\cdots$water configuration is disrupted in order to maximize the electrostatic interactions with the cation, shifting so that the tryptamine$\cdots$water interaction includes a $\pi$-hydrogen bond between the water and the phenyl ring of tryptamine. The infrared photodissociation spectra of K$^+$(Tryptamine)(H$_2$O)$_{n=1-4}$ and K$^+$(Tryptamine)(H$_2$O)$_{n=0-2}$Ar will be presented along with parallel \textit{ab initio} and thermodynamics calculations to assist with the identification of the isomers present in each experiment.

Description

Author Institution: Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, IL 61801

Keywords

Citation