MULTIPLE PATHWAYS IN THE VIBRATIONAL AUTOIONIZATION OF THE BENDING OVERTONES OF FORMYL RADICAL.

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1998

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Ohio State University

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Selected individual rotational levels in vibrational bands of the Renner-Teller split (020) and (030) systems in the 3pπ2Π Rydberg state of HCO have served as originating levels for vertical second-photon transitions to vibrationally autoionizing Rydberg series. Spectra of individual rotational levels associated with the (0200) and (0220) as well as the (0310) and (0330) states of HCO+ were obtained. Linewidths of assigned series convey information on autoionization dynamics. Series extrapolations determine anharmonic terms in the HCO+ bending potential.

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Author Institution: Department of Chemistry, Purdue University

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http://hdl.handle.net/1811/19153

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1990-1999