THz SPECTROSCOPY OF THE $a^{1}\Delta_{g}$ STATE OF O$^{18}$O and $^{18}$O$_2$

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2010

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Ohio State University

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Submillimeter-wave rotational spectra of O$^{18}$O and $^{18}$O$_2$ in the $a^{1}\Delta_{g}$ state have been detected in a new static discharge cell useful for studying rare isotopologues of transient molecules. Rotational transition frequencies of both species have been measured through 1.6 THz, to better than 1 part in $10^{7}$, allowing precise determination of molecular constants. The first measurements with our static discharge cell provide a check on the isotopic predictions in the $a^{1}\Delta_{g}$ state.

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Author Institution: Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109; I. Physikalisches Institut, Universitat zu Koln, Zulpicher Str. 77, Koln, Germany

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