FURTHER EPR AND ENDOR STUDIES OF DIPHENYLMETHYLENE

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1974

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Ohio State University

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The original magnetic resonance studies of dipheny Imethylene in single crystal $hosts^{1,2}$ have been extended. EPR and ENDOR experiments on diphenylmethylene in diphenylethylene, benzophenone, and 4-bromopheoyl ether will be discussed. The orientation and conformation of this ground state triplet in each of these hosts will be described, with a view toward the understanding of the differences in the $T_{1}$ $\leftarrow$ $T_{0}$ optical spectrum in each host.

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$^{1}$R. W. Brandon, G. L. Closs, C. E. Davoust, C. A. Hutchison, B, E. Kohler, and R. Silbey, J. Chem. Phys. 43, 2006 (1965). $^{2}$C. A. Hutchison and B. E. Kohler, J. Chem. Phys. 51, 3327 (1969).
Author Institution: Department of Chemistry, Harvard University

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