SPECTROSCOPY OF JET-COOLED p-DICHLOROBENZENE AND p-DICHLOROBENZENE - ARGON VAN DER WAALS COMPLEX

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1987

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Ohio State University

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Fluorescence excitation spectra have been obtained for p-dichlorobenzene in a pulsed supersonic expansion in He, Ar, and dilute Ar/He mixtures. Prominent in the spectra are vibronic features which have not been observed in previous spectra obtained under bulb conditions. Van der Waals features appear 30 1/cm and 60 1/cm to the red of bare molecule features and are identified as p-dichlorobenzene - argon van der Waals complexes containing one and two argon atoms, respectively.

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Author Institution: Department of Chemistry, VCU Box 2006

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