FTMW STUDIES OF HYDROGEN-BONDED TRIMERS$^{\ast}$

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1987

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Ohio State University

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Abstract

Rotational spectra have been observed with a Flygare FTMW spectrometer1 for a number of hydrogen-bonded trimers, most of which are linear and have the HCN dimer as a subunit. Spectroscopic constants have been determined, usually for several isotopic species of each trimer. Their values are given below for the Itain species. Symmetries, hydrogen-bond lengths and the separation of torsional and charge redistribution effects on the quarupolar hyperfine structure of 14N(Xa) will be discussed. [FIGURE]

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Work supported by NSF and PRF. 1 T.J. Balle and W.H. Flygare, Rev. Sci. Instrum. 52, 33 (1981).


Author Institution: Noyes Chemical Laboratory, University of Illinois

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