FTMW STUDIES OF HYDROGEN-BONDED TRIMERS$^{\ast}$

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1987

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Ohio State University

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Rotational spectra have been observed with a Flygare FTMW $spectrometer^{1}$ for a number of hydrogen-bonded trimers, most of which are linear and have the HCN dimer as a subunit. Spectroscopic constants have been determined, usually for several isotopic species of each trimer. Their values are given below for the Itain species. Symmetries, hydrogen-bond lengths and the separation of torsional and charge redistribution effects on the quarupolar hyperfine structure of $^{14}N (Xa)$ will be discussed. [FIGURE]

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$^{\ast}$ Work supported by NSF and PRF. $^{1}$ T.J. Balle and W.H. Flygare, Rev. Sci. Instrum. 52, 33 (1981).
Author Institution: Noyes Chemical Laboratory, University of Illinois

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http://hdl.handle.net/1811/17217

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1980-1989