SPECTRA OF COLD FLUOROBENZENE IONS WITH AN FT SPECTROMETER
Loading...
Date
1990
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
The spectra of several fluorobenzene cations have been generated by a corona discharge in a supersonic expansion. Rotational temperatures have been determined by computer simulation to be $80^{\circ}K$. The band origin of $C_{6}F_{6}$ determined with high precision compares well with that obtained by laser excitation $studies.^{1,2,3}$ trifluorobenzene cation spectra have been taken by the same technique and have been compared with matrix spectra. The rotatinal contour in the FT spectra are analyzed to identify the type of electronic transition.
Description
Author Institution: Laser Spectroscopy Facility, Department of Chemistry, The Ohio State University