JOINT THEORETICAL AND EXPERIMENTAL STUDIES OF $HeH_{2}{^{+}}$ POTENTIAL ENERGY SURFACES FOR $He^{+} + H_{2}$ REACTIONS

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1978

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Ohio State University

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In previous presentations1,2 we reported Hnl product detection experiments and preliminary theoretical studies and proton detection experiments for the He++H2 reaction processes. More extensive theoretical studies and ion detection scans have now been made and are reported. The theoretical studies include scans of the potential energy surfaces of the X2Σ+,22Σ+,32Σ+ and 12Π; states and surface cuts of the n2A1,12A,n2A1 and 12B1 states. The ion detection experiments involve the determination of relative cross sections and quantitative energy thresholds associated with the product ions H+,HeH+,H3+ and their deuterium analogs. Multi-surface pathways dominate.

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1 E. G. Jones, B. M. Hughes, D. G. Hopper, and T. O. Tiernan, Proc. 23rd ASMS, May 1975, Houston. 2 D. G. Hopper, A. C. Wahl, E. G. Jones, B. M. Hughes and T. O. Tiernan, Bull. Am. Phys, Soc, 22, 189 (1977). This research was supported in part by AFOSR.""


Author Institution: Science Applications Incorporated; Wright State University, Brehm Laboratory; Flammability Research Center, University of Utah

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