THE INFRARED SPECTRUM OF LIQUID HD

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1985

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Ohio State University

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We have measured the spectrum of liquid hydrogen deuteride in the region of the fundamental band (3500−4000cm−1) and of the pure rotational R(0) transition (80−90cm−1). The experiments were performed using a Bomem DA3.002 spectrometer and a 1 cm path; the liquid was followed along the gas-liquid coexistence line from 18 to 35 K. Of special interest are the effects of interference between the permanent dipole moment of HD and the transient dipoles induced during molecular collisions. These effects have been studied in the gas phase,1 and were also observed in solid HD.2 We observe a pronounced anomalous dispersion (Fano) lineshape for the R1(0) transition around 3715cm−1, whereas the R0(0) transition around 88cm−1 is only slightly asymmetric. A weak, sharp absorption feature was observed in the liquid at 18 K on the high frequency side of the broader Fano R1(0) profile; this feature resembles the beginning of the stronger sharp feature observed in the solid.2

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1N. H. Rich et al., Can. J. Phys. 61, 1648 (1983); 62, 1665, 1673 (1984). 2A. Crane and H. P. Gush, Can. J. Phys. 44, 373 (1966).


Author Institution: National Research Council of Canada, Herzberg Institute of Astrophysics; National Research Council of Canada, Herzberg Institute of Astrophysics; Department of Physics, Memorial University of Newfoundland

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