EXPERIMENTAL MAPPING OF THE ABSOLUTE VALUE OF THE ELECTRONIC TRANSITION DIPOLE MOMENT FUNCTION $\mu_{e}(R)$ OF THE $^{7}$Li$_{2}$ $A^{1}\Sigma^{+}_{u}-X^{1}\Sigma^{+}_{g}$ SYSTEM

Research Projects

Organizational Units

Journal Issue

Abstract

Continuous wave (CW) triple resonance laser spectroscopy} was used to map the absolute value of the electronic transition dipole moment function μe(R) of the 7Li2 A-X system. In this work, the transition dipole moment matrix elements of specific rovibronic molecular transitions were first determined by fitting the observed Autler-Townes splitting spectra. Then by employing the R-centroid approximation, or a multi-variable fit involving higher moments of R, μe(R) has been determined within a relatively large range of internuclear distance R. Finally, this electronic transition dipole moment function is compared with the ab initio calculations with very good agreement.

Description

Author Institution: Physics Department, Temple University, Philadelphia, PA 19122; Physics Department, Lehigh University, Bethlehem, PA 18015; Physics Department, Temple University, Philadelphia, PA 19122

Keywords

Citation