INFRARED SPECTROSCOPY OF SIZE-SELECTED CARBOCATIONS I.: C$_{3}$H$_{3}^{+}$, C$_{3}$H$_{5}^{+}$, AND C$_{4}$H$_{9}^{+}$
Loading...
Date
2008
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
Cold, rare gas tagged, gas phase carbocations are produced in a pulsed electric discharge supersonic expansion cluster source. The infrared spectra of the size-selected species are obtained \emph{via} infrared photodissociation spectroscopy. The structure and spectroscopy (700-4000 cm$^{-1}$) of the propargyl, cyclopropenyl, allyl, 2-propenyl, and t-butyl ions will be discussed. The infrared spectral signatures of the title ions are compared to the interstellar unidentified infrared emission bands.
Description
Author Institution: Department of Chemistry, University of Georgia, Athens, Georgia 30602.