THE $b ^{4}\Sigma^{-} \rightarrow a ^{4}\Pi_{i}$ TRANSITION OF THE NO MOLECULE

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1984

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Ohio State University

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Two sequences of the quartet system of $NO^{1}$ at 7900 {\AA} $(\Delta \nu = 4)$ and at 8700 {\AA} $(\Delta \nu = 3)$ have been rephotographed at high resolution. The spectra were obtained from a dc discharge in a supersonically expanding $jet^{2}$ of He + NO. The low rotational temperature achieved in the jet ($\sim 50 ^{\circ}K)$ results in a striking simplification of the previously very congested band structures, making it possible to proceed with a detailed rotational analysis.

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$^{1}$P.A. Freedman and P.L. Radloff, J. Mol. Spectrosc. 88, 225 (1981) $^{2}$A.T. Droege and P.C. Engelking, Chem. Phys. Lett. 96, 316 (1983)
Author Institution: Herzberg Institute of Astrophysics, National Research Council of Canada

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