VIBRATIONAL SPECTRA AND STRUCTURE OF PERFLUOROVINYL-DIFLUOROBORANE AND PERFLUOROVINYLDICHLOROBORANE

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1977

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Ohio State University

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Abstract

The infrared spectra of gaseous (3000-30 $cm^{-1}$) and solid (3000-200 $cm^{-1}$) perfluorovinyldifluoroborane and perfluorovinyldichloroborane have been recorded along with the Raman spectra (3000-30 $cm^{-1}$) of all three physical states. The vibrational data have been interpreted in detail and are consistent with a planar geometry for both compounds. The question of $\Pi$-delocalization through the C-B bond is discussed.

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Author Institution: Department of Chemistry, Furman University

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