DIODE LASER INTENSITY AND LINE WINTH MEASURENENTS IN THE $\nu_{1}$ AND ADJACENT ABSORPTION BANDS OF $N_{2}O$

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1980

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Ohio State University

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The intensities of individual rotation-vibration absorption lines of nitrous oxide (N2O) have been measured in the region 1210cm−1 to 1320cm−1 with a diode laser spectrometer. These include lines in the P and R branches of the fundamental (100−000) band of both isotopic species 14N216O and 14N218O, lines in the hot bands (11le0−01le0) and (111f0−011f0) of 14N216O, and several lines of the R branch of the (020−000) overtone band of 14N216O. These measurements were made at pressures 0.5 torr to 12 torr, resulting in line widths which were typically 3×10−3 cm−1. The spectra were recorded in digitized form and least-squares fit to a Voigt line profile. The individual line intensity measurements were then combined in a least-squares fit to obtain an integrated band intensity which will also be presented along with our estimate of the uncertainties The self-broadening of most of these lines has been measured. Measurements will be made of pressure broadening by N2.

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