FOURIER TRANSFORM EMISSION SPECTROSCOPY OF ScS

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2005

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Ohio State University

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The emission spectra of the A2ΠX2Σ+ and B2Σ+X2Σ+ systems of ScS have been observed in the 10000−13500 cm−1 region using a Fourier transform spectrometer. A rotational analysis of the 0−1, 0−0 and 1−0 bands of the A2Π3/2X2Σ+ and 0−1, 0−0, 1−0, 2−0 and 3−1 bands of the B2Σ+X2Σ+ systems has been obtained and improved spectroscopic constants have been extracted for the electronic states of ScS.

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Author Institution: Department of Chemistry, University of Arizona, Tucson, AZ 85721; Department of Chemistry, University of Waterloo, Waterloo, Ont., Canada N2L 3G1; Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287

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