FOURIER TRANSFORM EMISSION SPECTROSCOPY OF ScS
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Date
2005
Authors
Ram, R. S.
Bernath, P. F.
Steimle, T. C.
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
The emission spectra of the $A^{2}\Pi - X^{2}\Sigma^{+}$ and $B^{2}\Sigma^{+} - X^{2}\Sigma^{+}$ systems of ScS have been observed in the $10000-13500$ cm$^{-1}$ region using a Fourier transform spectrometer. A rotational analysis of the $0-1$, $0-0$ and $1-0$ bands of the $A^{2}\Pi_{3/2} - X^{2}\Sigma^{+}$ and $0-1$, $0-0$, $1-0$, $2-0$ and $3-1$ bands of the $B^{2}\Sigma^{+} - X^{2}\Sigma^{+}$ systems has been obtained and improved spectroscopic constants have been extracted for the electronic states of ScS.
Description
Author Institution: Department of Chemistry, University of Arizona, Tucson, AZ 85721; Department of Chemistry, University of Waterloo, Waterloo, Ont., Canada N2L 3G1; Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287