RYDBERG STATES CONVERGING TO HIGHER VIBRATIONALLY EXCITED STATES OF $HCO^{+}$.

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1998

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Ohio State University

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Abstract

Single rotational levels photoselected in the strongest bent $B^{2}A^{\prime}$ state of HCO serve as intermediate states in double resonance transitions to Rydberg states built on higher vibrationally excited levels of the linear $HCO^{+}$ core. Frank-Condon factors for the bent-to-linear transitions discriminate against resonances converging to lower lying vibrational states. Widths and intensities of multiple quantum vibrational autoionization resonances are affected by the level of core excitation.

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Author Institution: Department of Chemistry, Purdue University

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