RYDBERG STATES CONVERGING TO HIGHER VIBRATIONALLY EXCITED STATES OF $HCO^{+}$.
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Date
1998
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Publisher
Ohio State University
Abstract
Single rotational levels photoselected in the strongest bent $B^{2}A^{\prime}$ state of HCO serve as intermediate states in double resonance transitions to Rydberg states built on higher vibrationally excited levels of the linear $HCO^{+}$ core. Frank-Condon factors for the bent-to-linear transitions discriminate against resonances converging to lower lying vibrational states. Widths and intensities of multiple quantum vibrational autoionization resonances are affected by the level of core excitation.
Description
Author Institution: Department of Chemistry, Purdue University