SUBMILLIMETER-WAVE OBSERVATIONS OF C$_3$N$^-$ IN AN EXTENDED NEGATIVE GLOW DISCHARGE

Loading...
Thumbnail Image

Date

2009

Journal Title

Journal ISSN

Volume Title

Publisher

Ohio State University

Research Projects

Organizational Units

Journal Issue

Abstract

Extended negative glow and hollow anode discharges are found to be good sources of negative ions, such as CN$^-$, C$_2$H$^-$, and C$_4$H$^-$, for observations of pure rotational lines in the submillimeter-wave region, \textbf{129}, 244305 (2008)}. Thaddeus {\em et al.},\textit{Astrophys. J.}, \textbf{677},1132-1139 (2008)} detected C$_3$N$^-$ in a glow discharge in HC$_3$N diluted in Ar buffer gas, and its rotational lines up to 378 GHz ($J=39-38$) were measured. In the present investigation, this anion has been observed in an extended negative glow discharge in a gas mixture of C$_2$N$_2$ ($\sim 2$ mTorr) and C$_2$H$_2$ ($\sim 3$ mTorr) in Ar buffer gas of $\sim 15$ mTorr at the cell wall temperature of 230 K. The optimum discharge current was 2-4 mA with 250 Gauss longitudinal magnetic field. The rotational lines of up to $J=51-50$ in the 495 GHz region have been measured, and the improved rotational and centrifugal distortion constants are obtained. In the discharge optimum for production of C$_3$N$^-$, neither CN nor C$_3$N was detected with a similar signal accumulation time used for observations of the anion. However, this reaction has been found to be an excellent source for HC$_3$N, and the dominant formation mechanism of C$_3$N$^-$ is likely to be the dissociative electron attachment to HC$_3$N, \textit{New J. Phys.}, \textbf{8},117 (2006)}. The radiative association of C$_3$N with electrons seems to be unlikely at least for the extended negative glow discharge. Apparently HC$_3$N is synthesized by a fast neutral and neutral reaction,\textit{Chem. Phys. Lett.}, \textbf{211}, 461-468(1992); D. E. Woon and E. Herbst,\textit{Astrophys. J.}, \textbf{477}, 204-208(1997)}, %\begin{equation} \( {\rm C}_2{\rm H}_2 + {\rm CN} \rightarrow {\rm HC}_3{\rm N} + {\rm H}. \) %\end{equation} It is interesting to see that an isomer, HCCNC, is also detected in the discharge, although the number density of this species is found to be about two orders of magnitude smaller than that of HC$_3$N. Another isomer, HNCCC, has also been observed with much weaker signal intensity. This species might have been produced by the dissociative recombination reaction of HC$_3$NH$^+$ with electrons, although the detection of this cation has not been successful in this type of discharge.

Description

T. Amano, \textit{J. Chem. Phys.P. Thaddeus {\em et al.K. Graupner {\em et al.I. R. Sims {\em et al.
Author Institution: Department of Chemistry, University of Waterloo, Waterloo, ON, Canada N2L 3G1;

Keywords

Citation