THE INFRARED SPECTRA OF MATRIX ISOLATED OXIDES OF THE ALKALI METALS

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1969

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Ohio State University

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The infrared spectra of several oxides of alkali metal have been observed. These, formed by reaction of the metals with oxygen and trapped in a solid krypton matrix at $20^{\circ}K$, consist primarily of peroxides. $^{16}O-^{18}O$ isotope shifts have been used to facilitate the assignments and force constant calculations.

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Author Institution: Department of Chemistry, University of Pennsylvania

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