THE PURE ROTATIONAL SPECTRA OF DBr, HI, DI, $NH_{2}D, NHD_{2}$ FROM $40\mu-160\mu$

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1954

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Ohio State University

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Abstract

Fifteen rotation lines of DBr, fourteen of HI, and thirteen of DI have been measured. From the analysis, values for the reciprocal of inertia B and the centrifugal stretching constant D have been obtained for each compound. These are in agreement with values for these constants obtained from near infrared data. Using molecular constants for the deuterated ammonia molecules obtained from microwave data, the rotational spectrum of $NH_{2}D$ and $NHD_{2}$ have been calculated and an attempt has been made to fit the theoretical to the experimental spectrum.

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Note. Data were obtained on the far infrared spectrograph, construction of which was supported by Wright Air Development Center.
Author Institution: Department of Physics, The Ohio State University

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