NEW RESULTS IN ZERO-FIELD PARAMAGNETIC RESONANCE (ZFPMR) OF TRIVALENT GADOLINIUM IN SEVERAL DIAMAGNETIC HOSTS

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1974

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Ohio State University

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Abstract

Zero-field paramagnetic resonance (ZFPMR) $spectra^{1}$ for the ground S-state of trivalent gadolinium will be presented for a variety of diamagnetic hosts, including several ethylsulfates and several lattices having the fluorite structure. Special emphasis will be placed upon not only the zero-Field line shape, but also on new crystal field and hyperfine constants derived from zero-field spectra not previously available from conventional electron paramagnetic resonance spectra.

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This research was sponsored under grants from the National Science Foundation, Army Research Office (Durham), Office of Naval Research, and the Research Corporation. $^{1}$E. R. Bernstein and G. H. Dobbs, Rev. Sci. Instrum. 44, 1314 (1973).
Author Institution: Department of Chemistry, Princeton University

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