INFRARED AND RAMAN SPECTRA OF $Si(C \equiv CH)_{4}, Ge(C \equiv CH)_{4}$, AND $Sn(C \equiv CH)_{4}$

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1966

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Ohio State University

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Infrared spectra of $Si(C \equiv CH)_{4}, Ge(C \equiv CH)_{4}$, and $Sn(C \equiv CH)_{4}$ have been measured from 33 to $4000 cm^{-1}$ for the vapor and for solutions in several solvents. Raman spectra with polarizations were obtained for solutions. $T_{1}$ symmetry was assumed and was completely satisfactory. Fundamentals for species $a_{1}$ and $f_{2}$ could be assigned with little difficulty, but only a few of the Raman active e fundamentals were observed.

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Author Institution: Army Natick Labs.; Mellon Institute, Pittsburgh

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