LOWEST ELECTRONIC STATES OF $UO^{++}_{\ 2}$.

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1965

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Ohio State University

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Polarized luminescence excitation spectra absorption spectra and luminescence spectra of the uranyl ion ($UO^{++}_{\ 2}$) have been studied in glass matrices and as single crystals at room temperatures at $77^{\circ}K$ and at $4^{\circ}K$. The results quite definitely indicate that the lowest energy absorption band of $UO^{++}_{\ 2}$ consists of three distinct electronic transitions. Information on the species of these electronic states was also provided and will be discussed.

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Author Institution: Department of Chemistry, Louisiana State University

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