CURRENT RESEARCH ON HYDROGEN-BONDED COMPLEXES AT THE UNIVERSITY OF VALLADOLID
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Date
1999
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
Investigation of hydrogen-bonded heterodimers formed by the six-membered ring heterocycles tetrahydropyran or thiane with HCl has recently evidenced the formation of both axial and equatorial hydrogen $bonds^{ab}$. We have extended these studies to other complexes in which the proton acceptor molecule of the complex has non-equivalent binding sites. In this communication we present an analysis of the conformational preferences and structures of the hydrogen-bonded complexes theitane-HCl, methylenecyclobutane-HCl and cyclopentene oxide-HCl, investigated by molecule-beam Fourier transform microwave spectroscopy (MB-FTMW).
Description
$^{a}$ S. Antolinez, J.C. L\'{o}pez and J.L. Alonso, Angew, Chem., in press (1999) $^{b}$ M.E. Sanz, J.C. L\'{o}pez and J.L. Alonso, submitted (1999)
Author Institution: Departamento de Qufmica Fisica, Facultad de Ciencias, Universidad de Valladolid
Author Institution: Departamento de Qufmica Fisica, Facultad de Ciencias, Universidad de Valladolid