LASER EXCITATION OF THE $A^{2}\Pi - X^{2}\Sigma^{+}$ SYSTEM OF SROH

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1993

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Ohio State University

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Recently we have undertaken a rotational analysis of the $(100)-(000)$ and $(010)-(000)$ bands of the $A^{2}\Pi - X^{2}\Sigma^{+}$ system of SrOH. Preliminary results suggest a strong K-type resonance between the $(01^{0}0)\Sigma$ and $(01^{1}0)\Delta$ vibronic levels of the $A^{2}\Pi$ state. As for $BO_{2}^{1}$, this is expected in linear molecules for which $A >> c \omega_{2}$.

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$^{1}$ A. G. Adam, A. J. Merer and D. M. Steunenberg, J. Chem. Phys. 92, 2848 (1990).
Author Institution: Department of Chemistry, Dalhousie University

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