INTENSITIES OF ELECTRIC FIELD INDUCED TRANSITIONS OF AXIALLY SYMMETRIC MOLECULES.

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1967

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Ohio State University

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Using the method which Dows and $Buckingham^{1}$ applied to diatomic molecules, we have obtained expressions for the intensities of electric field induced transitions of axially symmetric molecules possessing a permanent dipole moment. Selection rules for these electric field spectra are found to be $\Delta J=0, \pm 2; \Delta K =0, \pm 1,\, \pm 2$. Observed frequencies would permit the determination of $A_{0}$ and other molecular parameters, while observed intensities would yield information on dipole moments.

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This research was supported by the National Science Foundation. Peter L. Willson is N.A.S.A. Trainee. $^{1}$ D. A. Dows and A. D. Buckingham, J. Mol, Spectry, 12, 189 (1964).
Author Institution: Department of Physics, Michigan State University

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http://hdl.handle.net/1811/15260

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1960-1969