AN EMISSION SYSTEM OF THE IO MOLECULE

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1959

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Ohio State University

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Abstract

A band system of the IO molecule, first observed by Coleman, Gaydon and Vaidya1 in emission from an oxyhydrogen flame to which methyl iodide was added, has been photographed under high resolution using a 21 ft. concave grating spectrograph. Approximately forty bands have been observed in the region 4000 to 7000 {\AA}. The rotational structure of the bands indicates that the transition is of the type 2Π2Π. The analysis of the bands and the molecular constants of IO will be discussed.

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1 Coleman, E.H., Gaydon, A. G. and Vaidya, W. M. Nature 162 , 108 (1948).


Author Institution: Division of Pure Physics, National Research Council, Ottawa

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