MCD SPECTRA OF METHYL IODIDE AND HYDROGEN IODIDE IN THE VACUUM ULTRAVIOLET

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1976

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Ohio State University

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The gas-phase magnetic circular dichroism (MCD) spectra of methyl iodide and hydrogen iodide will be reported for the spectral region ca. 1500-2000 {\AA}. Of specific interest are the absorption bands assigned to members of the first s-Rydberg spin-orbit manifold. The differences in the magnetic properties of these spin-orbit members can be observed in their MCD spectra and, therefore, a unique insight into their characterization is provided. The validity of existing assignments will be discussed.

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Author Institution: Department of Chemistry, Louisiana State University

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