HIGH RESOLUTION INFRARED SPECTRUM OF $CD_{3}F$: THE $\nu_{1}(A_{1})$ AND $2\nu_{5}(A_{1})$ PARALLEL $BANDS^{*}$

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1979

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Ohio State University

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The ν1(A1) and 2ν5(A1) bands have been recorded on the University of Tennessee five meter Littrow spectrometer with resolutions from 0.010 - 0.030cm−1. Approximately 200 lines in ν1 have been assigned. The band is perturbed above J = 12 but appears normal below this except for the K = 5 subband. Preliminary analysis of ν1 for the lines with J<15,K<10 yields ν0=2090.820±0.004 cm−1,α1A=(AA)=(2.040±0.006)×10−2 cm−1 and α1B=(BB)=−(1.815±0.020)×10−3 cm−1. The 2ν5 band near 2115cm−1 has also been assigned. Further analysis of these two bands including a GSCD analysis will be reported.

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Research supported by the Planetary Atmospheres program of the National Aeronautics and Space Administration under Grant NGL-43-001-006.


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