MEASUREMENT OF THE V-V ENERGY TRANSFER RATES FOR THE $CO-CS_{2}$ SYSTEM BETWEEN 198 AND 370 K
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Date
1974
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Ohio State University
Abstract
The V-V energy transfer rates for CO(v = 1) colliding with ground state $GS_{2}$ have been measured by observing the quenching of IR vibrational fluorescence between 198 and 370 K. This work presents evidence that the V-V rate is actually determined by a multiquantum process . Theoretical calculations assuming a multiquantum process have been performed for $CO(v = 1) + CS_{2} \rightarrow CO + CS_{2}$(101) and have been shown to be consistent with the experimental results.
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Author Institution: Department of Chemistry, University of California