SPECTROSCOPIC STUDY OF THE 6111 \AA BAND OF $NO_{2}$

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Date

1975

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Ohio State University

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Abstract

Laser-induced fluorescence has been used to rotationally analyze Che 6111 {\AA} vibrational band of vapor phase $NO_{2}$. P, Q, and R branches have been observed and assigned. Rotational constants similar to the 5935 {\AA} $band^{1}$ have been obtained. Perturbations have been detected through lifetime measurements of individual rotational lines under ``collision-free” conditions ($\leq$ 1 mTorr pressure).

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$^{1}$Charles G. Stevens and Richard N. Zare, J. Mol. Spectrosc, (accepted for publication).""
Author Institution: Department of Chemistry, Columbia University, New York

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