LASER INDUCED CHEMILUMINESCENCE STUDY OF $HgCl^{*} (B \to X)$ TRANSITION: FORMATION, RADIATION AND QUENCHING PROCESSES

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1978

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Ohio State University

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The formation, radiation, and quenching of HgC1(B2Σ+) have been investigated using a laser-induced chemiluminescence technique, Hg/Cl2/Ar mixtures were irradiated near 2537 {\AA} by a frequency-doubled nitrogen-pumped pulled dye laser. The Hg(3P1) produced reacted with Cl2 to yield HgCl(B2Σ+). The time behavior of the HgCl(B2Σ+)→HgCl(X2Σ+) chemiluminescence was analyzed to obtain the following preliminary results:[FIGURE]

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This work was supported by ARPA under contract number DASG6O-77-C-0058 and DASG60-77-C-0028. R. O. Hunter, JR. has been a Fannie and John Hertz Foundation Fellow, University of California at Irvine.""


Author Institution: Maxwell Laboratories Incorporated; Molecular Physics Laboratory

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