SOME VIBRATIONAL BANDS OF $DIAZOMETHANE^{*}$
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Date
1954
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Ohio State University
Abstract
Several parallel and perpendicular bands in $CH_{2}N_{2}$ have been resolved on a grating spectrometer, and the records have been analyzed. The best results were obtained for the following bands: For the N-N stretching band, $\sigma_{2}, \sigma_{0}=2102.2 K, B^{\prime\prime}=0.3713 K, (B^{\prime}-B^{\prime\prime})=-0.00055 K$; for the $C-N$ stretching band, $\sigma_{4}, \sigma_{0}=852.3 K, B^{\prime}= 0.3778 K, (B^{\prime}-B^{\prime\prime})=-0.00213 K$; for the perpendicular $C-H$ stretching band, $\sigma_{5}, \sigma_{0}=3150.7 K. (A^{\prime\prime}-B^{\prime\prime})=8.913 K, (A^{\prime}-B^{\prime})-8.731 K$.
Description
$^{*}$This work has been supported by the Office of Ordnance Research, U. S. Army, and by the Research Corporation of America.
Author Institution: Department of Chemistry, The University of Tennessee
Author Institution: Department of Chemistry, The University of Tennessee