THE DISSOCIATIVE RECOMBINATION OF $CH_{3}O^{+}$ AND $CD_{3}O^{+}$ CATIONS

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2006

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Ohio State University

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Reactions with the methoxy radical CH3O+ have found to be significant pathways of production and destruction of important interstellar molecules and ions like NH4+, NH3, H2O, H3O+ }. These processes compete with the dissociative recombination of the named ions. Therefore, measurements of the rates, cross-sections and branching ratios of the dissociative recombination of the iosotopomers CH3O+ and CD3O+ have been perfomed at the CRYRING storage ring located at Stockholm, Sweden. Preliminary evaluation of the data yielded a reaction rate coefficient of cm3mol−1s and $\ 8.4\ast 10^{-7}\left( \frac{T}{300}\right) ^{-0.62}\ $ cm3% mol−1s−1 for CH3O+ and CD3O+, respectively. Calculation of the branching ratios rendered the following branching ratios for the reaction channels leading to the fissure of the C-O bond:, CH2+OH \ (1.6%);\ D2O+CD  (2%), \ (6%) respectively. The rest of the dissociative recombination rates was contributed from channels leaving the C-O bond intact: 92% and 98% for CH3O+ and CD3O+, respectively. Contrary to the CH3OH2+ ion}, the pathways preserving the bond between the heavy atoms dominate.

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Author Institution: Roslagstullsbacken 5:310 ZIP 114 21 Stockholm Sweden

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