NMR STUDIES OR SOME HINDERED ETHANIC ROTATORS

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1963

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Ohio State University

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“Conformational free energy differences for several hindered ethanic rotators are obtained with the aid of an expression suited to such determinations fro ambient NMR measurements. Medium effects on free energy differences are discussed and quantitative data are presented for a number of systems. Reliability of the approach is compared with that of other NMR approaches used for obtaining similar data, and based on temperature dependence studies of the NMR parameters.”

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Author Institution: National Bureau of Standards

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