DIPOLE MOMENTS OF THE $\pi^{\ast}$ STATES OF FORMYL FLUORIDE AND DIFLUORODIAZIRINE
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Date
1966
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Ohio State University
Abstract
A study is made of the Stark effect on the high resolution electronic absorption spectra of formyl fluoride (HFCO) and difluorodiazirine $(CN_{2}F_{2})$. The transition involved is $n-\pi^{\ast}$. From splittings of the rotational $^{p}P$ lines (using polarized exciting light) the dipole moment of the excited $\pi^{\ast}$ is determined. In addition the Stark effect is used as an aid in the assignment of the $CN_{2}F_{2}$ rotational spectrum.
Description
Author Institution: Department of Chemistry, Harvard University