NMR AND IR STUDIES OF HYDROGEN BONDING. EFFECTS OF STERIC FACTORS ON VARIOUS SPECTRAL PARAMETERS
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Date
1966
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Ohio State University
Abstract
Thermodynamics and various spectral parameters accompanying heteroassociation were measured in three-component systems using NMR and IR techniques. Each system involved di-tert-butyl carbinol, $CCl_{4}$, and an organic base capable of acting as proton acceptor in the hydroxyl proton-proton acceptor hydrogen bond. Correlations between thermodynamic functions and spectral parameters were compared to those suggested in the literature for systems involving proton donors comparatively free of steric hindrance.
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Author Institution: Department of Chemistry, Kansas State University