Direct Measurement of the Transition Dipole Moment of the $\nu_{3}$ Asymmetric C-H Stretching Vibration of the Methyl Radical

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1995

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Ohio State University

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Abstract

A direct measurement of the transition dipole moment, μ3, of the ν3 asymmetric C-H stretching vibration of the methyl radical has been made in a transverse-flow reactor using laser-photolysis transient infrared absorption spectroscopy. Cyano (CN) radicals (and Cl atoms) were produced by excimer laser photolysis of ClCN at 193 nm and reacted with methane to give both CH3 and HCN (and HCl). The intensities of 18 rotational lines of the ν3 fundamental band were measured relative to the R(8) line of the ν3 C-H stretching vibration of HCN. The transition dipole moment of the methyl radical was determined to be μ3=0.0327±0.0027 D using the known absolute absorption cross section of the ν3 vibration of HCN.

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Author Institution: "Gas Phase Dynamics Group, Chemistry Division Argonne National Laboratory", Argonne, Illinois 60439.

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