APPLICATION OF `NEARLY LINEAR' FORMALISM TO HCN, HCP AND $H_{2}O$

Thumbnail Image

Files

1966-C-04.jpg (84.34 KB)

Date

1966

Authors

Journal Title

Journal ISSN

Volume Title

Publisher

Ohio State University

Research Projects

Organizational Units

Journal Issue

Abstract

The bending of a nearly linear molecule can be described by a two dimensional harmonic oscillator well, perturbed either by a Lorentzian1 or by a Gaussian2 hump. Both models give essentially the same result. In the present work the theory has been applied to the calculation of ΔG′s,α′s and DK′s of excited electronic states of HCN and HCP and also of the ground state of H2O.

Description

1 W. R. Thorson and I. Nakagawa, J. Chem. Phys, 33, 994 (1960). 2 R. N. Dixon, Trans. Farad. Soc. 60, 1363 (1964).


Author Institution: Division of Pure Physics, National Research Council

Keywords

Citation

URI

http://hdl.handle.net/1811/14981

Collections

Abstracts of OSU International Symposium on Molecular Spectroscopy 1960-1969