SPECTROSCOPIC STUDY OF $Rg-CH_{4} (Rg = Ar, Kr, Ne)$ IN THE $7 \mu m$ REGION

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1999

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Ohio State University

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The absorption spectra of several rare gas-methane $(Rg = Ar, Kr, Ne)$ van der Waals complexes associated with the $v_{4}$ fundamental vibration of $CH_{4}$ were investigated in the $7 \mu m$ region. The complexes were produced in a pulsed slit supersonic jet and detected by a tunable diode laser spectrometer. The observed transitions are related to the $R(0), P(1), Q(1)$ and R(1) transitions of the $CH_{4}$ molecule in the complex. Analysis of the data is in progress, and the results will be presented at the conference.

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Author Institution: I. Physikalisches Institut, Universit\""{a}t zu K\""{o}ln; Physical Chemistry Laboratory, Oxford University

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