ELECTRONIC ABSORPTION SPECTRA OF $VCl_{4}{^{*}}$

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1963

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Ohio State University

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“The near infrared band spectrum of $VCl_{4}$ vapor has been qualitatively interpreted, previously, in terms of a Jahn-Teller distortion of the molecule in the excited electronic state. The spectral studies have been extended to low temperatures. Results obtained for this band system over the temperature range $77^{\circ} K$ to $300^{\circ} K$ will be presented. Ultraviolet absorption spectra of $VCl_{4}$, rigorously separated from $VOCl_{3}$, will be reported and the spectra interpreted in terms of charge-transfer transitions.”

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$^{*}$Supported by the National Science Foundation and an Alfred P. Sloan Research Fellowship.
Author Institution: Noyes Chemical Laboratory, University of Illinois

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